By Stuart A. Rice
The Advances in Chemical Physics sequence provides the leading edge in each sector of the self-discipline and offers the sector with a discussion board for severe, authoritative reviews of advances. It presents a piece of writing framework that makes each one quantity a very good complement to complicated graduate periods, with contributions from specialists world wide and a convenient word list for simple reference on new terminology. This sequence is a superb advisor for college students and execs in chemical physics and actual chemistry, from academia, executive, and industries together with chemical compounds, prescription drugs, and polymers.
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Additional resources for Advances in Chemical Physics (Volume 143)
Another unanswered question was whether glass densiﬁcation after 20 GPa pressure at room-temperatures treatment and the one at 5–8 GPa and high-temperatures treatment are of a similar nature. Recent years have witnessed a signiﬁcant advance in the understanding of the behavior of glassy silica under compression. By using a strain gauge technique, direct in situ measurements of the relative volume of the glass in a wide range of pressures (0–10 GPa) and temperatures (30–730 K) have been conducted (see Fig.
At room temperature, these two transformations signiﬁcantly pressure overlap, whereas at higher temperatures, they can be conditionally separated. The pressure range for the second transformation is still debatable. Note that the recent study on the bonding changes in the SiO2 glass conducted by using an inelastic X-ray scattering technique  gives an unreliable estimate of the degree of coordination transformation. According to Ref. , the transformation in the SiO2 glass to the sixfold coordination state of silicon atoms is completed at P $ 20 GPa.
However, the high-density amorphous states HDA and VHDA also show an irreversible transition to LDA when heated to temperatures slightly below crystallization. LDA transformation at 110–115 K, namely shear elastic softening, bulk softening, and main volume jump . Whereas the ﬁrst stages involve structural relaxation, the ﬁnal stage is consistent with a ‘‘ﬁrst-order like’’ transition—that is, the amorphous–amorphous transition shows a complex nonergodic nature that involves more than one process .
Advances in Chemical Physics (Volume 143) by Stuart A. Rice